Chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Introduction it is well known that the stress corrosion cracking scc mechanism is caused by the combination of tensile stress and a corrosive medium. Chlorideinduced stress corrosion cracking tests and. In transgranular stress corrosion cracking tgscc, the cracks cut through the grains and are oblivious to the grain boundaries.
While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the. I believe that is an industry practice and not a code requirement but i could be wrong. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2. Stress corrosion cracking scc stress corrosion cracking is to bear the stress of the alloy in the corrosive environment because of strong expansion of the alternate failure pattern of a generic term. Chlorideinduced stress corrosion cracking tests and example aging management program darrell s. Effects of prior cold work and sensitization heat treatment. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620oc to 705oc, depending upon prior solution treating temperature. Generally, scc provokes 1 cracks and fractures with a. Stress corrosion cracking is a form of localized corrosion that. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. What causes stress corrosion cracking in pipelines.
Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Stress corrosion cracking scc of austenitic stainless steels of types 316. Stress corrosion cracking of steel and aluminum in sodium. Chloride stress corrosion cracking initiates from sites of localized pitting or crevice corrosion. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. Stress corrosion cracking scc is the formation and growth of crack through. Controlling stress corrosion cracking scc in order for scc to occur, we require a susceptible material, an environment that will cause cracking of that material and a high enough stress or stress intensity factor. Jan 22, 20 stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. All samples were extracted from known operating conditions from the field failures. Stress corrosion cracking in pipelines begins when small cracks develop on the external surface of buried pipelines. There are, consequently, a number of approaches that we can use to prevent scc, or at least to give an acceptable lifetime. This paper described the mechanism of chlorideinduced stress corrosion cracking of oil tube as a result of.
Stress corrosion cracking facts and how to reduce the risk. Scc is known as an insidious form of corrosion failure and it results in a significant drop in the mechanical strength only with little metal loss. Chlorideinduced stress corrosion cracking of 316 stainless. Transgranular stress corrosion cracking tgscc is a typical fracture mode for the scc system of stainless steels in chloride environments, characterized by riverlike fractographs 15. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile.
High chloride concentrations, resulting from high chloride levels in the makeup water andor high cycles of concentration will increase susceptibility. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. Liquid dye penetrant test systems must usually meet a standard for low chloride levels as do markers. These grades are stronger and more resistant to stress corrosion cracking than the austenitic grades, with better toughness than the ferritic grades.
Chloride stress corrosion cracking in austenitic stainless. Dunn nrcnmsssfst public meetingggy with nuclear energy institute on chloride induced stress corrosion cracking regulatory issue resolution protocol august 5, 2014. The initiation of crack is more dependent on chloride concentration but less dependent on temperature. Stress corrosion cracking scc can slowly destroy your brewery equipment without warning. Chloride is the main contributor to scc of stainless steels. A material failure may be accelerated by the combined effect of corrosion and mechanical stress. Austenitic stainless steels suffer from scc in chlorides, caustic, and. The most common type is transgranular stress corrosion cracking, scc, that may develop in concentrated chloride containing environments. Typical appearance of chloride stress corrosion cracking. Another way to look at alloy performance in resistance to stress corrosion. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. The appearance of aiscc is a function of the environmental rh. The surface concentration of hydrogen, oxygen, the hydroxide, and chloride.
Chloride stress corrosion cracking in austenitic stainless steel is characterized by. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Soilside chlorideinduced stress corrosion cracking under. Towards a more realistic experimental protocol for the. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. Stress corrosion cracking behavior of nickel base alloys. Stress corrosion cracking of brittle fracture surface, but it may also occur in high toughness materials. Stress corrosion cracking behavior in the transition.
Pdf stress corrosion cracking scc of nickelbased alloys. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most wellknown forms of scc in the refining and chemical processing industries. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Macroscopically, scc fractures have a brittle appearance. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. Chloride stress corrosion cracking in austentic hse. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range.
Stress corrosion cracking examples a fracture of the screwed side of a dshackle. Chlorideinduced stress corrosion cracking tests and example. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Stress corrosion cracking a material failure may be accelerated by the combined effect of corrosion and mechanical stress. Through an investigation of the field failure analysis and laboratory experiment, a study on stress corrosion cracking scc behavior of steel and aluminum was performed. Intergranular stress corrosion cracking of welded steel twi.
The general trend to use higher strength alloys peaked in 1950 with alloy 7178t651 used on the boeing 707, then the industry changed to using lower strength alloys. Stress corrosion cracking, residual stress, ammonia transporting pipeline 1. The results are explained in terms of comparison between the two concentrations of sodium chloride. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Chloride stress corrosion cracking clscc is one of the most common reasons. Stress corrosion cracking scc is a type of environmentallyassisted cracking eac, or the formation of cracks caused by various factors combined with the environment surrounding the pipeline.
The stress dependence of fracture appearance and parameters of time to cracking. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. Chloride induced stress corrosion cracking tests and example aging management program darrell s. Similar but accelerated laboratory test was subsequently conducted in such a way as to mimic the field failures. Despite the extensive qualification of inconel for specific applications, a number of corrosion problems have arisen with inconel tubing.
Stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. This is a typical location for residual stress, where metal deformation in construction of the shackle is at a maximum. The appearance of the fracture face is crystalline, although some rusting has taken place since the fracture. The stress corrosion cracking scc behavior perpendicular to the fusion line in the transition region between the alloy 182 nickelbase weld metal and the adjacent lowalloy reactor pressure vessel rpv steel of simulated dissimilar metal weld joints was investigated under boilingwater reactor normalwater chemistry conditions at different stress intensities and chloride. In refineries, this form of damage occurs as a result of catalyst movement in fcc reactorregenerator systems in catalyst handling equipment valves, cyclones, piping, reactors and slurry piping figure 443. Stress corrosion cracking scc of nickelbased alloys.
Now we get down to the last choice, chloride stress corrosion cracking cscc. Evaluation of stress corrosion cracking damage to an api. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Stress corrosion cracking scc is a common issue with many specialty alloys. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Maybe it isnt the last choice, but for this article it is.
Your tanks are the core of your brewery, so it is important to understand what scc is, what causes it, and what to do when your tanks suffer from this type of damage. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Stress corrosion cracking scc is cracking due to a process involving conjoint corrosion and straining of a metal due to residual or applied stresses. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. There is a synergistic relationship between dissolved oxygen and the chloride level. Temperature is a significant environmental factor affecting cracking. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. It can be detrimental to austenitic stainless steel, one of the main reasons these steels are not considered a cureall for corrosion problems. It requires a susceptible material and, depending on the material, sufficient levels of. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Stress corrosion cracking scc results from the combined action of three factors.
The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. The stress dependence of fracture appearance and parameters of time to cracking, and cracking growth. Behaviour of stress corrosion cracking of austenitic stainless. Stress corrosion cracking in the necessary condition is to have tensile strength. High chloride levels contribute to chloride stress corrosion cracking.
How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Corrosion is related to the susceptibility of the material to the environment, while stresses may be residual, external or. Chloride stress corrosion cracking is a localized corrosion mechanism like pitting and crevice corrosion. Mechanisms of stresscorrosion cracking asm international. Scc occurs as a result of a combination between corrosion and tensile stress.
Chloride stress corrosion involves selective attack of a metal along its grain boundaries. For example, chloride stress corrosion cracking of austenitic stainless steel. Chloride cracking of austenitic stainless steels 300 series ss is an offshoot of cui, and theres nothing really magical about it. Three underlying factors must be present to cause scc. Stress corrosion cracking behavior in the transition region.
The pitting and stress corrosion cracking of a stable austenitic stainless steel in aqueous chloride environments were investigated using a secondary ion mass spectrometer as the primary experimental technique. Duplex is comprised of an austenitic and ferrritic metallurigical structure iron, chrome, nickel, molybdenum, nitrogen. Previously, it was generally considered that an elevated temperature was necessary for scc to occur. Everywhere cracking has occurred it has always been in a region that sees a higher amount of. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Everywhere cracking has occurred it has always been in a region that sees a higher amount of stress, by several orders of magnitude. Stress corrosion cracking scc is the brittle failure of a metal by cracking under tensile stress in a corrosive environment.
The reason why steam condensate is commonly used to hydrotest ss piping. If you have insulated solid stainless steel equipment operating in the cui temperature range you are likely to eventually experience external chloride stress corrosion cracking ecscc. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. The effects of prior cold work cw and sensitization treatment on the stress corrosion cracking scc behaviour of type 304 stainless steels have been studied in chloride solutions using electrochemical tests and magnesium chloride tests with ubend specimen. It has been reported that the environmentalfracture is discontinuous at the micron scale 4. The most common type is transgranular stresscorrosion cracking, scc, that may develop in concentrated chloridecontaining environments. In all cases of failure by stress corrosion cracking, the following three factors must be present. Stress corrosion cracking the international institute of. Soilside chlorideinduced stress corrosion cracking under insulation a length of tp 304 stainless steel pipe in service as a high pressure steam condensate return in an outdoor underground environment beneath a sidewalk along a roadway suffered cracking near its welded ends, while the main body showed no visual signs of failure.
Stress corrosion cracking international institute of. Behaviour of stress corrosion cracking of austenitic. This paper described the mechanism of chloride induced stress corrosion cracking of oil tube as a result of improper material selection and lack of maintenance. The cracking mode appears to depend on the chloride level, with an increased chloride content tending to shift the cracking from intergranular to transgranular or mixed mode microstructure of materials subjected to ethanol scc are typicallyferrite, or ferrite and pearlite. Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur.